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Protonation constant (pKa) of MDEA in water as function of temperature and ionic strength

Abstract

An extension of the Debye-Hückel model was used to re-evaluate the MDEA protonation constant as a function of temperature and ionic strength. The Debye-Hückel limiting slope was estimated and the suggested parameters are successfully representing the data. The ionic strength was calculated by the speciation generated in the system and not only from the salt background concentration. Correlations for the protonation constant of MDEA were proposed for infinite dilution and high ionic strength and the standard thermodynamic properties for protonated MDEA were calculated.

Category

Academic article

Language

English

Author(s)

  • Ardi Hartono
  • Muhammad Saeed
  • Inna Kim
  • Hallvard Fjøsne Svendsen

Affiliation

  • Norwegian University of Science and Technology
  • SINTEF Industry / Process Technology

Year

2014

Published in

Energy Procedia

ISSN

1876-6102

Publisher

Elsevier

Volume

63

Page(s)

1122 - 1128

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