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Microstructure of multicrystalline silicon seeded by polysilicon chips and fluidized bed reactor granules

Abstract

Multicrystalline silicon displays a considerable smaller average grain size and reduced dislocation generation when being seeded by polycrystalline silicon chips or fluidized bed reactor silicon granules. A simple texture analysis shows how the initially random grain structure of the seeds develops a weak preference for near-〈111〉 and near-〈112〉 oriented grains upwards in the ingot. Closer investigations reveal a considerable coarsening of the initial microstructure of the seeds during the directional solidification process, especially for small fluidized bed reactor granules. The irregular shape of polysilicon chips allows for melt penetration into the seeding structure and potential indentation effects that may account for the increased dislocation generation observed in this case. The increased generation may, however, also be related to a higher ratio of ∑27 grain boundaries.

Category

Academic article

Language

English

Author(s)

Affiliation

  • Norwegian University of Science and Technology
  • SINTEF Industry / Sustainable Energy Technology
  • Institute for Energy Technology

Year

2016

Published in

Journal of Crystal Growth

ISSN

0022-0248

Publisher

Elsevier

Volume

441

Page(s)

95 - 100

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